Ozonolysis of five-membered heterocycles

Ozonolysis of five-membered heterocycles
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五元杂环的臭氧分解

DOI：
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发表时间：
1987
期刊：
影响因子：
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通讯作者：
Y. Omote
Y. Omote
中科院分区：
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文献类型：
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作者：
C. Kashima;S. Hibi;T. Maruyama;Kazuo Harada;Y. Omote

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评价了五元杂环与臭氧的相对反应速率。这些相对速率与相应环上的最高键序数值相关联，用方便的HMO方法计算。从这个关联性，杂环与臭氧的反应性能够被预测。含氧五元杂环臭氧化反应的主要产物是相应的羧酸，而含氮杂环则生成相应的酰胺。
The relative reaction rate of five-membered heterocycles with ozone was evaluated. These relative rates were correlated to the highest bond order value in the corresponding ring, calculated by the convenient HMO method. From this correlation, the reactivity of heterocycles with ozone was able to be predicted. Also it was concluded that the predominant product in the ozonolysis of five-membered heterocycles containing an oxygen atom was the corresponding carboxylic acid, while nitrogen heterocycles gave the corresponding amide.