CHELATE STABILIZATION OF A MONOMERIC LITHIUM TELLUROLATE
CHELATE STABILIZATION OF A MONOMERIC LITHIUM TELLUROLATE
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DOI：
10.1002/anie.199212601
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发表时间：
1992-09-01
期刊：
影响因子：
--
通讯作者：
EDELMANN, FT
中科院分区：
文献类型：
--
作者：
GORNITZKA, H;BESSER, S;EDELMANN, FT
可分离的、明确定义的碱金属碲酸盐--对于有机合成以及过渡金属碲化物的生产是感兴趣的--仅已知具有大体积有机基团。通过锂化和硫族化，碲酸盐3现在已经从1经由中间体2以定量产率获得。随后的反应证明了这种碲酸盐的有用性。
Isolable, well-defined alkali metal tellurolates-of interest for organic synthesis as well as for the production of transition metal tellurides-are only known with bulky organic groups, By lithiation and chalcogenation, the tellurolate 3 has now been obtained from 1 in quantitative yield via the intermediate 2. Subsequent reactions demonstrate the usefulness of such tellurolates.