Microwave Fourier Transform Spectroscopy of Perchloryl Fluoride:19F35/37Cl16O3and19F35/37Cl16O218O
Microwave Fourier Transform Spectroscopy of Perchloryl Fluoride:19F35/37Cl16O3and19F35/37Cl16O218O
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高氯酰氟的微波傅里叶变换光谱：19F35/37Cl16O3和19F35/37Cl16O218O
DOI：
10.1006/jmsp.1996.0016
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发表时间：
1996
期刊：
影响因子：
--
通讯作者：
M. Gerry
中科院分区：
文献类型：
--
作者：
H. Müller;M. Gerry
Abstract 18O-enriched, monolabeled perchloryl fluoride,19F35/37Cl16O218O, has been synthesized. Its rotational spectrum has been studied in the 4–22 GHz region. In addition, the spectra of the symmetric isotopomers19F35/37Cl16O3have been reinvestigated. Rotational and centrifugal distortion constants, as well as chlorine nuclear quadrupole and chlorine and fluorine spin–rotation and spin–spin coupling constants, have been determined for the ground vibrational state. The ground state rotational data have been used to evaluate geometrical parameters. The harmonic force field has been refined. The results are compared with data of related molecules.
