Observation of the "missing" polar OCS dimer.
Observation of the "missing" polar OCS dimer.
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DOI:
10.1063/1.2709879
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发表时间:
2007-02
期刊:
影响因子:
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通讯作者:
M. Afshari;M. Dehghani;Z. Abusara;N. Moazzen-Ahmadi;A. McKellar
中科院分区:
文献类型:
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作者:
M. Afshari;M. Dehghani;Z. Abusara;N. Moazzen-Ahmadi;A. McKellar
A new infrared band at 2069.3 cm-1 is observed and assigned to the long-anticipated polar isomer of the OCS dimer, helping to explain apparent discrepancies among earlier studies. The data reported here should enable direct observation of the microwave spectrum of polar (OCS)2 and motivate new theoretical works on the energetics of OCS dimer isomers and interconversion energy barriers.