Controlling the aqueous miscibility of ionic liquids: Aqueous biphasic systems of water-miscible ionic liquids and water-structuring salts for recycle, metathesis, and separations

Controlling the aqueous miscibility of ionic liquids: Aqueous biphasic systems of water-miscible ionic liquids and water-structuring salts for recycle, metathesis, and separations
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DOI:
10.1021/ja0351802
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发表时间:
2003-06-04
影响因子:
15
通讯作者:
Rogers, RD
Rogers, RD
中科院分区:
化学1区
文献类型:
--
作者:
Gutowski, KE;Broker, GA;Rogers, RD

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亲水性离子液体可以从水溶液中盐析和浓缩,当加入亲液盐时形成水性两相体系,如1-丁基-3-甲基咪唑氯化物([C4 mim]Cl)和K3 PO 4的混合物的相行为所示。
Hydrophilic ionic liquids can be salted-out and concentrated from aqueous solution upon addition of kosmotropic salts forming aqueous biphasic systems as illustrated by the phase behavior of mixtures of 1-butyl-3-methylimidazolium chloride ([C4mim]Cl) and K3PO4.