Selective rearrangement of terminal epoxides into methylketones catalysed by a nucleophilic rhodium-NHC-pincer complex.

Selective rearrangement of terminal epoxides into methylketones catalysed by a nucleophilic rhodium-NHC-pincer complex.
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DOI：
10.1039/c4cc07154a
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发表时间：
2015-01
期刊：
Chemical communications
影响因子：
4.9
通讯作者：
E. Jürgens;Barbara Wucher;F. Rominger;K. Törnroos;Doris Kunz
E. Jürgens;Barbara Wucher;F. Rominger;K. Törnroos;Doris Kunz
中科院分区：
化学2区
文献类型：
--
作者：
E. Jürgens;Barbara Wucher;F. Rominger;K. Törnroos;Doris Kunz

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研究了Rh（I）-NHC-钳形催化剂在温和条件下对单烷基环氧化物Meinwald重排反应的催化性能。亲核环氧化物开环由刘易斯酸辅助。
An efficient Rh(I)-NHC-pincer catalyst for the highly regioselective Meinwald rearrangement of monoalkylated epoxides into methylketones under mild conditions is presented. The nucleophilic epoxide opening is assisted by Lewis acids.