Novel Ferrocene Derivatives with PH-Functionalized Phosphanylalkylcyclopentadienyl Ligands: Syntheses and Molecular Structures ofrac-[Fe{(η5-C5H4)CMe2PHR}2] (R = Ph, Mes) andrac-[Fe{(η5-C5H4)CMe2PHPh(Cp*TaCl4)}2]
Novel Ferrocene Derivatives with PH-Functionalized Phosphanylalkylcyclopentadienyl Ligands: Syntheses and Molecular Structures ofrac-[Fe{(η5-C5H4)CMe2PHR}2] (R = Ph, Mes) andrac-[Fe{(η5-C5H4)CMe2PHPh(Cp*TaCl4)}2]
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具有 PH 官能化膦酰基烷基环戊二烯基配体的新型二茂铁衍生物：ofrac-[Fe{(η5-C5H4)CMe2PHR}2] (R = Ph, Mes) andrac-[Fe{(η5-C5H4)CMe2PHPh(Cp*TaCl4) 的合成和分子结构)}2]
DOI：
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发表时间：
2002
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影响因子：
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通讯作者：
E. Hey‐Hawkins
中科院分区：
文献类型：
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作者：
Thomas Höcher;S. Blaurock;E. Hey‐Hawkins
6，6-二甲基富烯与LiPHMes（Mes = 2，4，6-Me 3C 6 H2）反应得到Li[（C5 H4）CMe 2 PHMes]（1）。以锂试剂Li[（C_5H_4）CMe_2PHR]（R = Ph，Mes）和FeCl_2为原料，高产率地合成了二茂铁衍生物rac-[Fe{（η_5-C_5H_4）CMe_2PHR}_2] [R = Ph（2），Mes（3）]。化合物2与[Cp* TaCl 4]反应得到异三核配合物rac-[Fe{（η5-C5 H4）CMe 2 PHPh（Cp* TaCl 4）}2]（4）。化合物1 - 4通过光谱进行表征，并对2 - 4进行晶体结构测定。（© Wiley-VCH Verlag GmbH，69451魏因海姆，德国，2002）
6,6-Dimethylfulvene reacts with LiPHMes (Mes = 2,4,6-Me3C6H2) to give Li[(C5H4)CMe2PHMes] (1). The ferrocene derivatives rac-[Fe{(η5-C5H4)CMe2PHR}2] [R = Ph (2), Mes (3)] are obtained in high yield from the lithium reagents Li[(C5H4)CMe2PHR] (R = Ph, Mes) and FeCl2. Compound 2 reacts with [Cp*TaCl4] to give the heterotrinuclear complex rac-[Fe{(η5-C5H4)CMe2PHPh(Cp*TaCl4)}2] (4). Compounds 1−4 were characterized spectroscopically, and crystal structure determinations were carried out on 2−4. (© Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)