Electrochemical fluorination: state of the art and future tendences
Electrochemical fluorination: state of the art and future tendences
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DOI：
10.1016/j.jfluchem.2003.07.002
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发表时间：
2004-02-02
影响因子：
1.9
通讯作者：
Gambaretto, GP
中科院分区：
文献类型：
--
作者：
Conte, L;Gambaretto, GP
简要介绍了ECF法制备全氟有机化合物的工艺过程。全氟产品的产率取决于实验条件和起始材料的性质。一些有用的规则报告，以优化ECF过程。通过改进操作技术，使二吗啉丙烷和N-甲基吗啉同时酯化得到高收率的全氟二吗啉丙烷（PF 4S）。(C)2003 Elsevier B. V.保留所有权利。
A brief survey of the ECF process for the preparation of perfluorinated organo-compounds is given. The yield of perfluorinated products depends on the experimental conditions and on the nature of the starting material. Some useful rules are reported in order to optimise the ECF process. An improved operational technique allowed to obtain high yield of perfluorodimorpholinepropane (PFDMP) by simultaneous fluorination of dimorpholinepropane and N-methylmorpholine. (C) 2003 Elsevier B.V. All rights reserved.