Double-layered honeycomb architectures constructed via hierarchical self-assembly of hexagonal spin crossover cobalt(ii) metallacycles
Double-layered honeycomb architectures constructed via hierarchical self-assembly of hexagonal spin crossover cobalt(ii) metallacycles
复制标题
通过六方自旋交叉钴(ii)金属环的分层自组装构建双层蜂窝结构
DOI：
10.1039/d0cc02628j
复制
发表时间：
2020
影响因子：
4.9
通讯作者：
Hayami Shinya
中科院分区：
文献类型：
--
作者：
Akiyoshi Ryohei;Kuroiwa Keita;Sakuragi Mina;Yoshimoto Soichiro;Ohtani Ryo;Nakamura Masaaki;Lindoy Leonard F.;Hayami Shinya
六方钴(II)金属环及其“脂质包装”衍生物[Co6(R-bisterpy)6]X12（R = H，OC16H33，OC27H55；X = BF4，C12-Glu）已被合成和表征。掺入 BF4− 阴离子的化合物形成球状聚集体，而含有 C12-Glu 脂质阴离子的化合物则形成由六边形堆叠管状结构组成的双层蜂窝结构，表现出自旋交叉行为。
A hexagonal cobalt(II) metallacycle and its “lipid packaged” derivatives, [Co6(R-bisterpy)6]X12 (R = H, OC16H33, OC27H55; X = BF4, C12-Glu), have been synthesized and characterized. The compounds incorporating BF4− anions formed sphere-like aggregates while the compounds with C12-Glu lipid anions gave double-layered honeycomb architectures composed of hexagonal stacked tubular structures, which exhibit spin crossover behaviour.