Sulfate removal by Desulfovibrio sp CMX in chelate scrubbing solutions for NO removal

Sulfate removal by Desulfovibrio sp CMX in chelate scrubbing solutions for NO removal
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通过 Desulfovibrio sp CMX 在螯合物洗涤溶液中去除硫酸盐,以去除 NO

DOI:
10.1016/j.biortech.2013.06.037
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发表时间:
2013-09-01
影响因子:
11.4
通讯作者:
Shi, Zhuang
Shi, Zhuang
中科院分区:
工程技术1区
文献类型:
--
作者:
Chen, Mingxiang;Zhang, Yu;Shi, Zhuang

文献摘要

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为研究生物脱硫脱氮过程中可能引入的Fe螯合物和亚硝基络合物(Fe(II)EDTA-NO)对硫酸盐去除过程的影响,研究了硫酸盐还原菌脱硫弧菌(Desulfovibrio sp. CMX)在Fe螯合物和Fe(II)EDTA-NO存在下的硫酸盐去除能力,同时研究了Fe(II)EDTA-NO的还原作用. Fe(II)EDTA和Fe(III)EDTA的添加可以刺激硫酸盐还原性能。Fe(II)EDTA-NO对菌株有抑制作用,但CMX能通过消耗乳酸存活,去除Fe(II)EDTA-NO后恢复其硫酸盐还原活性。硫酸盐还原可以提高在较高的Fe(II)EDTA-NO浓度(2和4 mM)的乳酸盐施加在实验的中间阶段,和72.2%和62.6%的硫酸盐在182小时内被去除,分别。在这项研究中,90%以上的Fe(II)EDTA-NO(0.25-4 mM)在60小时内被去除,这比硫酸盐还原快得多。(C)2013爱思唯尔有限公司保留所有权利。
To study the effects of Fe chelate solution and nitrosyl-complex (Fe(II)EDTA-NO), which might be introduced in the simultaneous biodesulfurization and denitrification process, on the sulfate removal process, a sulfate reducing bacteria Desulfovibrio sp. CMX was investigated for its sulfate removal capacity in the presence of Fe chelate additives and Fe(II)EDTA-NO. Meanwhile, Fe(II)EDTA-NO reduction was also investigated. The addition of Fe(II)EDTA and Fe(III)EDTA could stimulate the sulfate reduction performance. Although Fe(II)EDTA-NO could inhibit the strain, CMX could survive by consuming lactate and recover its sulfate reducing activity after Fe(II)EDTA-NO removed. Sulfate reduction could be enhanced in higher Fe(II)EDTA-NO concentrations (2 and 4 mM) by lactate applied at the middle stage of the experiment, and 72.2% and 62.6% sulfate were removed in 182 h, respectively. In this study, above 90% Fe(II)EDTA-NO (0.25-4 mM) was removed less than 60 h, which was much faster than sulfate reduction. (C) 2013 Elsevier Ltd. All rights reserved.