Study towards diversity oriented synthesis of optically active substituted cyclopentane fused carbocyclic and oxacyclic medium-sized rings: Competition between Grubbs-II catalyzed ring closing olefin metathesis and ring closing carbonyl-olefin metathesis
Study towards diversity oriented synthesis of optically active substituted cyclopentane fused carbocyclic and oxacyclic medium-sized rings: Competition between Grubbs-II catalyzed ring closing olefin metathesis and ring closing carbonyl-olefin metathesis
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DOI：
10.1007/s12039-016-1197-7
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发表时间：
2016-12-01
影响因子：
1.7
通讯作者：
Roy, S. C.
中科院分区：
文献类型：
--
作者：
Chakraborty, P.;Roy, S. C.
对光学活性环戊烷稠合双环骨架的多样性合成进行了研究。从市售的起始原料（S）-香芹酮制备通用中间体。Grubbs-II催化的闭环复分解（RCM）和闭环羰基烯烃复分解（RCCOM）之间的竞争的观察是研究的关键特征。
A study towards diversity-oriented synthesis of optically active cyclopentane fused bicyclic frameworks has been accomplished. The common intermediate was prepared from commercially available starting material (S)-carvone. The observations on competition between Grubbs-II catalyzed ring closing metathesis (RCM) and ring closing carbonyl-olefin metathesis (RCCOM) were the key features of the study.