Ruthenium .pi.-Complexes of o-Benzoquinone
Ruthenium .pi.-Complexes of o-Benzoquinone
复制标题
钌.pi.-邻苯醌络合物
DOI:
10.1021/om00016a044
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发表时间:
1994
期刊:
影响因子:
2.8
通讯作者:
A. Powell
中科院分区:
文献类型:
--
作者:
D. Bohle;K. Carron;A. Christensen;P. Goodson;A. Powell
The oxidative addition of catechol to triruthenium dodecacarbonyl results in either tetranuclear ([Ru2 (t7V-M2-02C6H4)(CO) 4] 2, la) or hexanuclear ([Rusto^^-C^ CetD (CO) 8] 2, 2) complexes which contain x-bound o-benzoquinone ligands. Lewis bases readily add to these complexes to give either the mononuclear complexes Ru (t? 2-02C6H3R)(CO) 2 {EPh3} 2 (3a-d: R=