Rhodium Catalyzed ortho-Cyanation of Arylphosphates with N-cyano-N-phenyl-p-toluenesulfonamide
Rhodium Catalyzed ortho-Cyanation of Arylphosphates with N-cyano-N-phenyl-p-toluenesulfonamide
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DOI：
10.1002/cctc.201301076
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发表时间：
2014-05-01
期刊：
影响因子：
4.5
通讯作者：
Ding, Hong-Yan
中科院分区：
文献类型：
--
作者：
Gu, Li-Jun;Jin, Cheng;Ding, Hong-Yan
本文描述了一种以Rh为催化剂的螯合辅助CH键的氰化反应。该工艺为高产率制备多种2-氰基芳基膦酸酯及相关化合物提供了一种有效的方法。该反应可容忍多种合成上重要的官能团。
A rhodium-catalyzed cyanation of chelation assisted CH bonds is described. This process provided a useful method for the preparation of diverse 2-cyanated arylphosphonate and related compounds in good yields. The reaction tolerates a variety of synthetically important functional groups.