1,5-Asymmetric induction during nucleophilic additions to arenetricarbonylchromium complexes: tricarbonyl(eta(6)-1-methyl-4-{spiro[(1R,2S)-1,7,7-trimethylbicyclo[2.2.1]heptane-3,2'-1,3-dioxolan]-2-yloxy}benzene)chromium.
1,5-Asymmetric induction during nucleophilic additions to arenetricarbonylchromium complexes: tricarbonyl(eta(6)-1-methyl-4-{spiro[(1R,2S)-1,7,7-trimethylbicyclo[2.2.1]heptane-3,2'-1,3-dioxolan]-2-yloxy}benzene)chromium.
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芳烃三羰基铬络合物亲核加成过程中的 1,5-不对称诱导：三羰基(eta(6)-1-甲基-4-{螺[(1R,2S)-1,7,7-三甲基双环[2.2.1]庚烷-3
DOI：
10.1107/s0108270108004666
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发表时间：
2008
期刊：
影响因子：
--
通讯作者：
Pinkerton,AAlan
中科院分区：
文献类型：
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作者：
Paramahamsan,Harinandini;Pearson,AnthonyJ;Pinkerton,NathalieM;Pinkerton,AAlan
The tricarbonylchromium unit bound to the arene ring of the chiral title complex, [Cr(C19H26O3)(CO)3], is rotated by ca 25° in agreement with the proposed mechanism for 1,5-asymmetric induction of nucleophilic attack.
