The freezing process in methanol-, ethanol-, and propanol-water systems as revealed by differential scanning calorimetry
The freezing process in methanol-, ethanol-, and propanol-water systems as revealed by differential scanning calorimetry
复制标题
差示扫描量热法揭示甲醇、乙醇和丙醇-水系统中的冷冻过程
DOI：
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发表时间：
1997
期刊：
影响因子：
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通讯作者：
T. Wakabayashi
中科院分区：
文献类型：
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作者：
K. Takaizumi;T. Wakabayashi
用差示扫描量热法(DSC)测定了甲醇、乙醇和丙醇-水体系的固液相图，包括亚稳态相。对这三种体系在冷却过程中最初形成的亚稳固相进行了检测，以分析凝固过程，并将亚稳相的形成与溶液结构联系起来。
Solid-liquid phase diagrams, including metastable phases, have been obtained by differential scanning calorimetry (DSC) for methanol-, ethanol-, and propanol-water systems. The metastable solid phases which are initially formed on cooling were detected for these three systems, in order to analyze the freezing processes and to correlate the formation of the metastable phases with solution structure.