Synthesis of Monofluoroalkenes via the Activation of Allylic C-F Bonds: A Novel Route to β-Aminofluoroalkenes Using Pd-Catalyzed Allylic Amination Reactions of 3,3-Difluoropropenes

Synthesis of Monofluoroalkenes via the Activation of Allylic C-F Bonds: A Novel Route to β-Aminofluoroalkenes Using Pd-Catalyzed Allylic Amination Reactions of 3,3-Difluoropropenes
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DOI:
10.1055/s-0030-1259333
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发表时间:
2011-02-01
期刊:
影响因子:
2
通讯作者:
Paquin, Jean-Francois
Paquin, Jean-Francois
中科院分区:
化学4区
文献类型:
--
作者:
Paquin, Jean-Francois

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本文描述了一种新的和有效的β-氨基氟烯烃的合成路线的发展,从容易获得的3,3-二氟丙烯和胺,通过烯丙基C-F键的活化进行。
This article portrays the development of a novel and efficient synthetic route to beta-aminofluoroalkenes, from readily available 3,3-difluoropropenes and amines, that proceeds via the activation of an allylic C-F bond.