Solvent as structure directing agent for the synthesis of novel coordination frameworks using a tripodal flexible ligand
Solvent as structure directing agent for the synthesis of novel coordination frameworks using a tripodal flexible ligand
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DOI：
10.1039/b812645c
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发表时间：
2008-11
期刊：
影响因子：
3.1
通讯作者：
Sujit K. Ghosh;S. Kitagawa
中科院分区：
文献类型：
--
作者：
Sujit K. Ghosh;S. Kitagawa
通过柔性三羧酸配体和 Cd(II) 金属离子在二甲基甲酰胺 (DMF)、二乙基甲酰胺 (DEF) 和异丙醇 (PrOH) 中自组装合成了三种新型三维 (3D) 配位聚合物，其中不同尺寸和形状的溶剂的变化导致形成具有不同孔径和形状的溶剂模板中性和阴离子框架，如 X 射线晶体学所示。
Three novel three-dimensional (3D) coordination polymers have been synthesized by the self-assembly of a flexible tricarboxylate ligand and Cd(II) metal ion in dimethylformamide (DMF), diethylformamide (DEF) and isopropanol (PrOH), where changes of solvent with different size and shape lead to the formation of solvent templated neutral and anionic frameworks with different pore sizes and shapes as shown by X-ray crystallography.