Dielectric functions of ferroelectric Pb0.5Sr0.5TiO3 film determined by transmittance spectroscopy
Dielectric functions of ferroelectric Pb0.5Sr0.5TiO3 film determined by transmittance spectroscopy
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DOI：
10.1088/0022-3727/42/21/215403
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发表时间：
2009-10
期刊：
影响因子：
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通讯作者：
Jing Yang;Yanqing Gao;Zhiming Huang;Xiangjian Meng;M. Shen;H. Yin;Jinglan Sun;J. Chu
中科院分区：
文献类型：
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作者：
Jing Yang;Yanqing Gao;Zhiming Huang;Xiangjian Meng;M. Shen;H. Yin;Jinglan Sun;J. Chu
Pb0.5Sr0.5TiO3 (PST) films having a pure polycrystalline perovskite phase and well-grown grains were prepared by a chemical solution deposition method. Their optical response from 1.1 to 5.0 eV was investigated by transmittance spectroscopy, and the complex dielectric functions and optical parameters were evaluated in terms of the Tauc–Lorentz and Cauchy models. The direct optical band energy of the interband transition from the valence to conduction bands was determined to be 4.09 eV. Below this fundamental absorption region, the optical response in the energy range of 3–4 eV behaves as a local-states-related Urbach-band-tail absorption with the tail energy of about 243 meV. By fitting the refractive index using a single oscillator model, it is found that the optical dispersion of the PST films in the transparent region (1–3 eV) may originate mainly from the direct interband critical point transition between the valence and conduction bands.
