\-Cyclodextrin-catalyzed effects on the hydrolysis of esters of aromatic acids

\-Cyclodextrin-catalyzed effects on the hydrolysis of esters of aromatic acids
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-环糊精对芳香酸酯水解的催化作用

DOI:
10.1007/bf00664101
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发表时间:
1987
期刊:
Journal of inclusion phenomena
影响因子:
--
通讯作者:
Yongming Huang
Yongming Huang
中科院分区:
--
文献类型:
--
作者:
Dao;N. Huang;L. Xue;Yongming Huang

文献摘要

被引文献

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In order to make the behavior of the hydrophobic cavity of β-cyclodextrin clear, we have studied β-cyclodextrin-catalyzed hydrolysis of a series of nitrophenyl esters of aromatic acids. We defined a new kinetic parameter to determine the structure of the inclusion compounds. The kinetic parameters obtained provide evidence that the aromatic acid moiety rather than the nitrophenyl moiety of the esters mainly enters the hydrophobic cavity of β-cyclodextrin to form the inclusion complex.