ARGENTATION EQUILIBRIA OF SUBSTITUTED STYRENES
ARGENTATION EQUILIBRIA OF SUBSTITUTED STYRENES
复制标题
DOI：
10.1021/ja01080a007
复制
发表时间：
1965-01-01
影响因子：
15
通讯作者：
FURUKAWA, J
中科院分区：
文献类型：
--
作者：
FUENO, T;OKUYAMA, T;FURUKAWA, J
结论实验误差对K和e的影响是重要的，应分析其对K和e的影响。这似乎是显而易见的，但是当人们考虑到文献中基于错误数据的电子给体=受体复合物的讨论量时，或者考虑到对差异的讨论，例如不同溶剂中K的“不同”值，这可能在实验误差范围内吻合得很好，那么似乎确实值得强调这一结论。也许可以提出进一步的标准来检验这些复合物的实验数据的可靠性，这将使文献中大量的数据得到严格的使用，应该指出，文献中很少有关于供体-受体复合物的数据能经受住AK的严格检验（AK> 3个标准差）。失败并不一定意味着复合物实际上不存在，或者它们的平衡常数与报道的值有很大的不同。这只是意味着怀疑是有道理的。最后，我们注意到，为了比较的目的，将来自不同复合物的数据制成表格时，这种表格将K和e分开时的危险。因为使用EQ。
ConclusionThe major conclusion which can be stated is that ex-perimental error is important, and its effect on K and e should be analyzed. This may seem obvious, but when one considers the amount of discussion in the literature of electron donor= acceptor complexes based upon erroneous data, or the discussion of discrepancies, such as “different” values of K in different solvents, which may agree well within the experimental error, then it does seem worthwhile emphasizing this conclu-sion. Perhaps further criteria for testing the reliability of the experimental data for these complexes may be stated whichwould permit critical use of the extensive data in the literature.It should be noted that there are probably few data on donor-acceptor complexes in the literature which can survive the rigorous test on AK (AK> 3 standard de-viations). Failure does not necessarily mean that the complexes do not really exist or that their equilibrium constants are drastically different from the reported values. It just means that skepticism is warranted. Finally, we note the danger in tabulating data from different complexes for comparison purposes when such tabulation separates K and e. Because the use of eq.