[Zn2 (thf)2 (EtZn)6 Zn4 (μ4 -O)(tBuPO3 )8 ]: A Dodecanuclear Zincophosphonate Aggregate with a Zn4 (μ4 -O) Core.

[Zn2 (thf)2 (EtZn)6 Zn4 (μ4 -O)(tBuPO3 )8 ]: A Dodecanuclear Zincophosphonate Aggregate with a Zn4 (μ4 -O) Core.
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DOI:
10.1002/(sici)1521-3773(19990301)38:5
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发表时间:
1999-03
期刊:
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通讯作者:
Yu Yang;J. Pinkas;M. Noltemeyer;H. Schmidt;H. Roesky
Yu Yang;J. Pinkas;M. Noltemeyer;H. Schmidt;H. Roesky
中科院分区:
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文献类型:
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作者:
Yu Yang;J. Pinkas;M. Noltemeyer;H. Schmidt;H. Roesky

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合成的最大的多核锌骨架是标题化合物(见图),它包含的结构特征与层状和三维磷酸锌和磷酸锌中发现的基序密切相关。这些活性中心使得这种膦酸锌成为合成多孔膦酸锌材料的可行前体。
The largest multinuclear zinc framework synthesized is in the title compound (see picture), which contains structural features closely related to the motifs found in layered and three-dimensional zincophosphates and zincophosphonates. The reactive centers make this zincophosphonate a viable precursor for the synthesis of porous zincophosphonate materials.