Iron(II) Tris(3-bromo-1,10-phenanthroline) Complex: Synthesis, Crystal Structure and Electropolymerization
Iron(II) Tris(3-bromo-1,10-phenanthroline) Complex: Synthesis, Crystal Structure and Electropolymerization
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三(3-溴-1,10-菲咯啉)铁(II)配合物：合成、晶体结构和电聚合
DOI：
10.5012/bkcs.2002.23.3.399
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发表时间：
2002
期刊：
影响因子：
--
通讯作者：
Bu
中科院分区：
文献类型：
--
作者：
K. Lee;I. Yoon;Shim;Bu
合成了三（3-Br-phen）（3-Br-phen; 3-溴-1，10-邻菲咯啉）铁（II）配合物作为电聚合的前驱体，并研究了其晶体结构.室温下，在乙腈中，将[Fe（3-Br-phen）3] 2+还原性电聚合到玻碳电极和氧化铟锡（ITO）光学透明电极表面。聚[Fe（3-Br-phen）3] 2+膜附着在玻碳电极上，具有良好的电活性和稳定性。形成的薄金属聚合物膜也证实了吸收光谱。
The complex of iron(II) tris(3-Br-phen) (3-Br-phen; 3-bromo-1,10-phenanthroline) was prepared as a precursor of electropolymerization and the crystal structure of [Fe(3-Br-phen) 3](PF6)2·CH3CN with a distorted octahedral geometry has been investigated. The reductive electropolymerization of [Fe(3-Br-phen) 3] 2+ complex onto the surface of a glassy carbon electrode and indium tin oxide (ITO) optically transparent electrode were performed in acetonitrile at room temperature. Thin film of poly-[Fe(3-Br-phen) 3] 2+ formed was adherent, electroactive and stably deposited on a glassy carbon disk electrode. The thin metallopolymeric film formed was also confirmed by absorption spectroscopy.