Diels-Alder Reaction of Isobenzofurans/Cyclopentadienones with Tetrathiafulvalene: Preparation of Naphthalene, Fluoranthene, and Fluorenone Derivatives.

Diels-Alder Reaction of Isobenzofurans/Cyclopentadienones with Tetrathiafulvalene: Preparation of Naphthalene, Fluoranthene, and Fluorenone Derivatives.
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异苯并呋喃/环戊二烯酮与四硫富瓦烯的 Diels-Alder 反应:萘、荧蒽和芴酮衍生物的制备。

DOI:
10.1021/acs.orglett.7b03686
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发表时间:
2018
期刊:
影响因子:
5.2
通讯作者:
A. Mohanakrishnan
A. Mohanakrishnan
中科院分区:
化学1区
文献类型:
--
作者:
J. Karunakaran;A. Mohanakrishnan

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1,3-二芳基苯并[c]呋喃/环戊二烯酮与TTF的Diels-Alder反应,随后三氟甲磺酸介导的所得加合物的裂解导致相应的1,4-二芳基取代的萘、荧蒽和芴酮的形成。还报道了代表性的二芳基取代烃的物理化学性质。
Diels-Alder reaction of 1,3-diarylbenzo[c]furan/cyclopentadienone with TTF followed by triflic acid mediated cleavage of the resulting adducts led to the formation of the respective 1,4-diaryl substituted naphthalenes, fluoranthenes, and fluorenones. The photophysical properties of representative diaryl-substituted hydrocarbons are also reported.