Thiazolylimines as novel ligand-systems for spin-crossover centred near room temperature.
Thiazolylimines as novel ligand-systems for spin-crossover centred near room temperature.
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DOI：
10.1039/c6dt02077a
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发表时间：
2016-09
影响因子：
4
通讯作者：
N. Struch;N. Wagner;G. Schnakenburg;R. Weisbarth;S. Klos;J. Beck;A. Lützen
中科院分区：
文献类型：
--
作者：
N. Struch;N. Wagner;G. Schnakenburg;R. Weisbarth;S. Klos;J. Beck;A. Lützen
发展了一种新的铁(II)络合物的噻唑亚胺配体体系，它能在室温附近的T1/2温度下稳定溶液和固体中的自旋交叉。在溶液和固体状态下研究了这一效应。此外，还研究了晶体堆积效应，给出了不同的t1/2甚至是以-3°C为中心的固态磁滞。
A new thiazolylimine ligand system for iron(ii) complexes which stabilises spin-crossover in solution and solid states with T1/2 temperatures around room temperature has been developed. This effect is studied in solution and solid states. Furthermore crystal packing effects are investigated offering a variety of T1/2 and even hysteresis centred at -3 °C in the solid state.