A domino approach to dibenzopentafulvalenes by quadruple carbopalladation.
A domino approach to dibenzopentafulvalenes by quadruple carbopalladation.
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DOI：
10.1002/anie.201307793
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发表时间：
2013-12
影响因子：
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通讯作者：
Jan Wallbaum;Roman Neufeld;D. Stalke;D. Werz
中科院分区：
文献类型：
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作者：
Jan Wallbaum;Roman Neufeld;D. Stalke;D. Werz
一举四得：四重多米诺碳钯化反应提供了获得高度取代的二苯并五富瓦烯和完整的五富瓦烯主链仅在一个合成步骤中构建。通过X射线晶体学和循环伏安法评估了结构和电子性质。
Four at one stroke: A quadruple domino carbopalladation reaction gives access to highly substituted dibenzopentafulvalenes and the complete pentafulvalene backbone is constructed in only one synthetic step. Structural and electronic properties have been evaluated by X‐ray crystallography and cyclovoltammetry.