Chiral catalysts confined in porous hosts: 1. Synthesis
Chiral catalysts confined in porous hosts: 1. Synthesis
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限制在多孔主体中的手性催化剂：1.合成
DOI：
10.1016/s0021-9517(02)00154-9
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发表时间：
2003
影响因子：
7.3
通讯作者：
T. Maschmeyer
中科院分区：
文献类型：
--
作者：
H. M. Hultman;M. Lang;M. Nowotny;I. Arends;U. Hanefeld;R. Sheldon;T. Maschmeyer
将手性二铑甲酰胺催化剂固定在MCM-41的孔内和低表面积二氧化硅（Aerosil 200）上。通过一个手性配体与羧酸酯系链基团的配体交换固定催化剂。在第二部分中报道了这些催化剂的催化活性。
Chiral dirhodium carboxamide catalysts were immobilised inside the pores of MCM-41 and on a low-surface-area silica (Aerosil 200). The catalysts were immobilised via ligand exchange of one chiral ligand with a carboxylate tether group. In part 2 the catalytic activity of these catalysts is reported.