Hydrogen charging effects on the alternation of oxide film formed on Ni, Cr and Alloy 690 in high-temperature water

Hydrogen charging effects on the alternation of oxide film formed on Ni, Cr and Alloy 690 in high-temperature water
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高温水中充氢对Ni、Cr和690合金氧化膜交替的影响

DOI:
10.1016/j.corsci.2022.110704
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发表时间:
2022-10
期刊:
影响因子:
8.3
通讯作者:
Tetsuo Shoji
Tetsuo Shoji
中科院分区:
材料科学1区
文献类型:
--
作者:
Jian Xu;Jing Nong;Fengrui Liang;Sui Yuan;Lu Ren;Qi Guo;Tetsuo Shoji

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研究了在高温水中充氢对镍、铬及690合金氧化膜的影响。在实验过程中,氢气被充电到样品中。充氢后,铬的内层出现非晶化。充氢后,镍的氧化膜变薄,沿内氧化层和基体边界观察到大量空洞。690合金的氧化膜表现出镍和铬的混合特征。氢扩散到溶液中,不仅影响了氧化物的热稳定性,而且阻碍了外层氧化物的析出。
The effects of hydrogen charging on the oxide film of Ni, Cr and Alloy 690 in high-temperature water were studied. Hydrogen was charged to the specimen during experiments. The inner layer of Cr exhibited amorphization after the hydrogen charging. The oxide film became thinner for Ni after hydrogen charging, and lots of cavities were observed along the boundary of inner oxide and matrix. The oxide film of Alloy 690 exhibited a mixed feature of Ni and Cr. The hydrogen diffusing to the solution not only affected the thermal stability of the oxide but also hindered the precipitation of outer oxide.
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