Ruthenium and Rhodium‐Catalyzed Carbonylation Reactions
Ruthenium and Rhodium‐Catalyzed Carbonylation Reactions
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DOI：
10.1002/cctc.201200069
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发表时间：
2012-04
期刊：
影响因子：
4.5
通讯作者：
Xiao‐Feng Wu;H. Neumann
中科院分区：
文献类型：
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作者：
Xiao‐Feng Wu;H. Neumann
在过去的几十年里，羰基化反应已被公认为学术和工业研究的重要化学转化。羧酸衍生物是羰基化反应的主要产物，广泛应用于有机合成和精细化学品的制备。羰基化反应可以增加母体分子的碳链，同时引入羰基。本文综述了钌和铑催化羰基化反应的主要进展。与钯催化剂相比，钌和铑催化的反应在温和和无膦的条件下是活化C-OH键的有效方法。
Over the last few decades, carbonylation reactions have been accepted as important chemical transformations for both academic and industrial research. Carboxylic acid derivatives are the main product of carbonylation and are widely used in organic synthesis and fine chemicals preparation. Carbonylation reactions can increase the carbon chain of parent molecules, while introducing a carbonyl group. Herein, the main developments on ruthenium‐ and rhodium‐catalyzed carbonylation are summarized. Compared with palladium catalysts, ruthenium and rhodium catalyzed reactions are a powerful method for activating CH bonds under mild and phosphine free conditions.