Cure reaction and phase behavior of liquid crystalline epoxides-anhydride systems

Cure reaction and phase behavior of liquid crystalline epoxides-anhydride systems
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液晶环氧化物-酸酐体系的固化反应和相行为

DOI:
10.1016/j.cclet.2006.12.040
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发表时间:
2007-02
影响因子:
9.1
通讯作者:
Ren, Shao Ping
Ren, Shao Ping
中科院分区:
化学1区
文献类型:
--
作者:
Lu, Man Geng;Zheng, Yi Quan;Liang, Li Yan;Ren, Shao Ping

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A series of novel liquid crystalline epoxides with lateral substituents were cured with anhydrides and the cure kinetics was investigated by non-isothermal DSC technique. The results showed that the lengths of lateral substituents have great effect on the value of Ea. The curing reaction became less active, when the liquid crystalline epoxides have long lateral substituents and were controlled by diffusion at the late stage of cure. A nematic structure was observed by POM and XRD.
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