The chemistry of cationic polyphosphorus cages--syntheses, structure and reactivity.

The chemistry of cationic polyphosphorus cages--syntheses, structure and reactivity.
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DOI:
10.1039/c4cs00019f
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发表时间:
2014-09-21
影响因子:
46.2
通讯作者:
Weigand JJ
Weigand JJ
中科院分区:
化学1区
文献类型:
--
作者:
Holthausen MH;Weigand JJ

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本综述的目的是对阳离子聚磷笼的化学进行全面的综述。本综述的目的是对阳离子聚磷笼的化学进行全面的综述。重点介绍了为它们的制备建立的合成方案,这些方案都是基于P4的官能化,以及它们耐人寻味的后续化学。此外,本综述旨在促进无机、有机、催化和面向材料的化学界对多磷笼状化合物的广泛领域的兴趣。从长远来看,这将有助于开发新的合成程序,使P4功能化,并将其转化为(有机)磷化合物和具有附加值的材料。
The aim of this review is to provide a comprehensive view of the chemistry of cationic polyphosphorus cages. The aim of this review is to provide a comprehensive view of the chemistry of cationic polyphosphorus cages. The synthetic protocols established for their preparation, which are all based on the functionalization of P4, and their intriguing follow-up chemistry are highlighted. In addition, this review intends to foster the interest of the inorganic, organic, catalytic and material oriented chemical communities in the versatile field of polyphosphorus cage compounds. In the long term, this is envisioned to contribute to the development of new synthetic procedures for the functionalization of P4 and its transformation into (organo-)phosphorus compounds and materials of added value.
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