Tri-chain hydrocarbon surfactants as designed micellar modifiers for supercritical CO2.

Tri-chain hydrocarbon surfactants as designed micellar modifiers for supercritical CO2.
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DOI:
10.1002/anie.200901543
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发表时间:
2009-06
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通讯作者:
M. Hollamby;Kieran Trickett;A. Mohamed;Stephen Cummings;R. Tabor;O. Myakonkaya;Sarah Gold;S. Rogers;R. Heenan;J. Eastoe
M. Hollamby;Kieran Trickett;A. Mohamed;Stephen Cummings;R. Tabor;O. Myakonkaya;Sarah Gold;S. Rogers;R. Heenan;J. Eastoe
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作者:
M. Hollamby;Kieran Trickett;A. Mohamed;Stephen Cummings;R. Tabor;O. Myakonkaya;Sarah Gold;S. Rogers;R. Heenan;J. Eastoe

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实践:低成本碳氢化合物表面活性剂可充当超临界二氧化碳 (scCO(2)) 的流体改性剂。表面活性剂链末端支化的增加有助于胶束的形成(见中图:CO(2) 绿色),更多的链允许水被结合(右图,蓝色)。
Getting their feet wet: Low-cost hydrocarbon surfactants act as fluid modifiers for supercritical carbon dioxide (scCO(2)). Increased terminal branching of the surfactant chains aids micelle formation (see middle picture: CO(2) green), and more chains allows water to be incorporated (right, blue).