On the scaling of the critical temperature with the degree of polymerization in symmetric polymer blends

On the scaling of the critical temperature with the degree of polymerization in symmetric polymer blends
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关于对称聚合物共混物中临界温度与聚合度的关系

DOI:
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发表时间:
1992
期刊:
影响因子:
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通讯作者:
K. Schweizer
K. Schweizer
中科院分区:
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文献类型:
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作者:
A. Yethiraj;K. Schweizer

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通过一种新的分子封闭方法,研究了对称聚合物共混体系的临界温度(Tc)随聚合度(N)的变化规律.该理论预言了Tc-N,这与经典平均场思想定性一致。
The scaling of the critical temperature (Tc) with the degree of polymerization (N) in symmetric polymer blends is investigated via a new molecular closure to the polymer reference interaction site model integral equation theory. The theory predicts Tc∼N, which is qualitatively consistent with classical mean field ideas.