Comparison of molecular conductance between planar and twisted 4-phenylpyridines by means of two-dimensional phase separation of tetraphenylporphyrin templates at a liquid-HOPG interface
Comparison of molecular conductance between planar and twisted 4-phenylpyridines by means of two-dimensional phase separation of tetraphenylporphyrin templates at a liquid-HOPG interface
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DOI：
10.1039/c1cc12041g
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发表时间：
2011-01-01
影响因子：
4.9
通讯作者：
Matsuda, Kenji
中科院分区：
文献类型：
--
作者：
Sakano, Takeshi;Higashiguchi, Kenji;Matsuda, Kenji
合成了四苯基卟啉（TPP）氯化铑与平面和扭曲4-苯基吡啶衍生物的配位化合物。通过2-D相分离技术拍摄STM图像，并评估电导。这些苯基吡啶之间的表观高度的差异反映了配体的电导比。
Tetraphenylporphyrin (TPP) rhodium chlorides coordinated by planar and twisted 4-phenylpyridine derivatives were synthesized. An STM image was taken by a 2-D phase separation technique and the conductance was evaluated. Difference in apparent height between these phenylpyridines reflects the conductance ratio of ligands.