Novel Triarylimidazole Redox Catalysts: Synthesis, Electrochemical Properties, and Applicability to Electrooxidative C-H Activation
Novel Triarylimidazole Redox Catalysts: Synthesis, Electrochemical Properties, and Applicability to Electrooxidative C-H Activation
复制标题
DOI：
10.1021/ol300195c
复制
发表时间：
2012-03-02
期刊：
影响因子：
5.2
通讯作者：
Little, R. Daniel
中科院分区：
文献类型：
--
作者：
Zeng, Cheng-chu;Zhang, Ni-tao;Little, R. Daniel
描述了一种基于三芳基咪唑骨架的新型无金属、易于合成的氧化还原催化剂。通过迄今为止合成的那些，人们可以访问大约大约的潜在范围。 410毫伏。它们被证明是在温和条件下激活苄基 C-H 键的有用介体。
A new class of metal-free, easy to synthesize redox catalysts based on a triarylimidazole framework is described. With those synthesized thus far, one can access a potential range of ca. 410 mV. They proved to be useful mediators for the activation of benzylic C-H bonds under mild conditions.