An intramolecular substitution of hydroperoxy-endoperoxide to a bis-endoperoxide.
An intramolecular substitution of hydroperoxy-endoperoxide to a bis-endoperoxide.
复制标题
氢过氧-内过氧化物到双-内过氧化物的分子内取代。
作者：
Nurhan Kishali;E. Şahin;Yunus Kara
[反应：见正文] 以四氢萘为原料，开发出了一种新的立体定向合成双内过氧化物。四氢萘的光氧化导致氢过氧-内过氧化物的形成。氢过氧-内过氧化物的溴化反应生成双-内过氧化物，其确切构型已通过X射线分析确定。双内过氧化物的最低能量构象是船椅形式。
[reaction: see text] A new and stereospecific synthesis for bis-endoperoxide has been developed starting from tetrahydronaphthalene. Photooxygenation of tetrahydronaphthalene resulted in the formation of hydroperoxy-endoperoxide. The bromination reaction of hydroperoxy-endoperoxide gave bis-endoperoxide, whose exact configuration has been determined by X-ray analysis. The lowest-energy conformer of bis-endoperoxide is the boat-chair form.