Regio- and stereoselective hydrostannation of allenes using dibutyliodotin hydride (Bu2SnIH) and successive coupling with aromatic halides

Regio- and stereoselective hydrostannation of allenes using dibutyliodotin hydride (Bu2SnIH) and successive coupling with aromatic halides
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DOI:
10.1039/b712998j
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发表时间:
2007-12-14
影响因子:
4.9
通讯作者:
Baba, Akio
Baba, Akio
中科院分区:
化学2区
文献类型:
--
作者:
Hayashi, Naoki;Kusano, Kazunao;Baba, Akio

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用二正丁基碘化锡氢化物(Bu2SnIH)对烯烃进行区域和立体选择性氢锡化反应,得到α,β-二取代乙烯基锡,一锅法合成多取代烯烃。
Regio- and stereoselective hydrostannation of allenes by using di-n-butytliodotin hydride (Bu2SnIH) was accomplished to give alpha,beta-disubstituted vinyltins, which induced the synthesis of multisubstituted alkenes in a one-pot procedure.