An Ultraviolet Nonlinear Optic Borate with 13-Ring Channels Constructed from Different Building Units
An Ultraviolet Nonlinear Optic Borate with 13-Ring Channels Constructed from Different Building Units
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由不同建筑单元构建的具有 13 环通道的紫外非线性光学硼酸盐
DOI：
10.1021/acs.inorgchem.7b00975
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发表时间：
2017
影响因子：
4.6
通讯作者：
Yang GY
中科院分区：
文献类型：
--
作者：
Wang Er-Rong;Huang Jian-Hao;Yu Su-Juan;Lan You-Zhao;Cheng Jian-Wen;Yang Guo-Yu;Cheng JW;Yang GY
在溶剂热条件下，合成了一种椅式开放骨架硼酸盐Na2B9O15(H2O)(H3O)(1)。化合物1显示了沸石的规则孔以及硼酸盐的非线性光学(NLO)性质。氧化硼骨架的大的13环通道是由B3O7和B6O13的不同团簇单元和三环单元构成的。二次谐波(SHG)信号强度与KH_2PO_4(KDP)相似，且随着颗粒尺寸的增大而逐渐增大。化合物1具有短波长吸收边，是一种很有潜力的紫外非线性光学材料。
Under solvothermal conditions, a chair open-framework borate, Na2B9O15(H2O)(H3O) (1), has been synthesized. Compound1shows regular pores of zeolites as well as nonlinear optical (NLO) properties of borates. The large 13-ring channels of the boron oxide framework are constructed from different cluster units of B3O7and B6O13with three-ring units. The second harmonic generation (SHG) signal intensity of1is similar to that of KH2PO4(KDP) and gradually increased with larger particle size. Compound1is a potential UV NLO material for its short wavelength absorption edge.