The densely fluorinated nanospace of a porous coordination polymer composed of perfluorobutyl-functionalized ligands
The densely fluorinated nanospace of a porous coordination polymer composed of perfluorobutyl-functionalized ligands
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DOI：
10.1039/c4cc04505j
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发表时间：
2014-01-01
影响因子：
4.9
通讯作者：
Kitagawa, Susumu
中科院分区：
文献类型：
--
作者：
Jeon, Hyung Joon;Matsuda, Ryotaro;Kitagawa, Susumu
合成了一种全氟丁基功能化的二维多孔配位聚合物（PCP） {[Cu(bpbtp)(L)(DMF)]中心点（DMF）}(n) (H（2)bpbtp = 2,5-二（全氟丁基）对苯二甲酸，L = 2,5-二（全氟丁基）-1,4-二（4-吡啶基）苯，DMF = n， n -二甲基甲酰胺）。PCP的孔表面装饰有垂坠的全氟丁基，形成密集的氟化纳米空间，从而具有独特的气体吸附性能。
A perfluorobutyl-functionalized two-dimensional porous coordination polymer (PCP), {[Cu(bpbtp)(L)(DMF)]center dot(DMF)}(n) (H(2)bpbtp = 2,5-bis(perfluorobutyl) terephthalic acid, L = 2,5-bis(perfluorobutyl)-1,4-bis(4-pyridyl)benzene, DMF = N, N-dimethylformamide) has been synthesized and structurally characterized. The pore surface of the PCP is decorated with pendant perfluorobutyl groups which fabricate a densely fluorinated nanospace resulting in unique gas sorption properties.