Asymmetric binary acid catalysis: chiral phosphoric acid as dual ligand and acid
Asymmetric binary acid catalysis: chiral phosphoric acid as dual ligand and acid
复制标题
不对称二元酸催化：手性磷酸作为双配体和酸
DOI：
10.1039/c2cc34288j
复制
发表时间：
2013-01-01
影响因子：
4.9
通讯作者：
Luo, Sanzhong
中科院分区：
文献类型：
--
作者：
Lv, Jian;Luo, Sanzhong
近年来，在金属催化的背景下，手性Bronsted酸作为双配体和酸催化剂得到了发展。由于手性Bronsted酸和金属催化剂的弱配位行为，这种二元催化体系能够协同整合它们。由此产生的二元酸催化剂使一系列烯烃/芳烃的有效反应成为可能，超出了典型酸催化的范围。这篇专题文章总结了我们在开发不对称二元酸催化方面的努力。
Recently, chiral Bronsted acids as dual ligand and acid catalysts in the context of metal catalysis have been developed. Such binary catalytic systems synergistically integrate chiral Bronsted acids and metal catalysts as a result of their weakly coordinating behaviors. The resulting binary acid catalysts have enabled effective reactions of a range of olefins/aromatics, beyond the scope of typical acid catalysis. Our endeavors in developing asymmetric binary acid catalysis are summarized in this feature article.