Synthesis, Structures and Reactions of Novel 9,10‐Dihydro‐9,10‐distannaanthracenes
Synthesis, Structures and Reactions of Novel 9,10‐Dihydro‐9,10‐distannaanthracenes
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新型9,10-二氢-9,10-二锡蒽的合成、结构和反应
DOI：
10.1002/ejic.200300382
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发表时间：
2004
影响因子：
2.3
通讯作者：
M. Yoshioka
中科院分区：
文献类型：
--
作者：
Masaichi Saito;N. Henzan;Minehiko Nitta;M. Yoshioka
改进了9,10-二氢-9,10- distannathrens的合成方法，并将其应用于新型不对称9,10-二氢-9,10- distannathrens的合成。通过9,9,10,10-四卤（对甲氧基苯基）-9,10-二氢-9,10-丹丹蒽的卤化反应，成功合成了第一批9,9,10,10-四卤-9,10-二氢-9,10-丹丹蒽。用x射线分析确定了新合成的9,10-二氢-9,10- distannathr蒽的结构。（©Wiley-VCH Verlag GmbH & Co. KGaA，德国Weinheim 69451, 2004）
A method for the synthesis of 9,10-dihydro-9,10-distannaanthracenes has been improved and applied to the synthesis of novel unsymmetrical 9,10-dihydro-9,10-distannaanthracenes. The first 9,9,10,10-tetrahalo-9,10-dihydro-9,10-distannaanthracenes were successfully synthesized by halogenation of 9,9,10,10-tetrakis(p-methoxyphenyl)-9,10-dihydro-9,10-distannaanthracene. The structures of the newly obtained 9,10-dihydro-9,10-distannaanthracenes were determined by X-ray analysis. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)