THE CRYSTAL STRUCTURE OF [BEDT-TTF][Ni(dmit)2]. A NEW ROUTE TO DESIGN OF ORGANIC CONDUCTORS
THE CRYSTAL STRUCTURE OF [BEDT-TTF][Ni(dmit)2]. A NEW ROUTE TO DESIGN OF ORGANIC CONDUCTORS
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[BEDT-TTF][Ni(dmit)2] 的晶体结构。
DOI：
10.1246/cl.1985.191
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发表时间：
1985
影响因子：
1.6
通讯作者：
Y. Sasaki
中科院分区：
文献类型：
--
作者：
H. Kobayashi;R. Kato;A. Kobayashi;Y. Sasaki
在电荷转移配合物晶体中，[BEDT-TTF][Ni（dmit）2]、BEDT-TTF和Ni（dmit）2分子松散地堆积在一起，形成混合堆积柱。然而，分子间的横向相互作用表明，BEDT-TTF分子形成并排链。[BEDT-TTF][Ni（dmit）2]为有机金属的设计提供了一条新的途径。
In the crystal of the charge transfer complex, [BEDT-TTF][Ni(dmit)2], BEDT-TTF and Ni(dmit)2 molecules are loosely stacked to form mixed-stacking columns. However, the intermolecular transverse interaction indicates that the BEDT-TTF molecules form a side-by-side chain. [BEDT-TTF][Ni(dmit)2] suggests a new route to design of organic metals, despite of its semiconductive behavior.