Expansion of Dendrimer Template Function for Subnanoparticle Synthesis
Expansion of Dendrimer Template Function for Subnanoparticle Synthesis
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DOI：
10.1246/cl.210316
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发表时间：
2021-09-01
影响因子：
1.6
通讯作者：
Yamamoto, Kimihisa
中科院分区：
文献类型：
--
作者：
Kambe, Tetsuya;Li, Meijia;Yamamoto, Kimihisa
研究了苯基甲基树状大分子模板中PtBr4在THF中异常复合物的形成。这些特性使得通过改变树状大分子的溶剂组成来逆序组装铂盐成为可能。这种逆序装配方法使金属杂交比例的全范围调整成为可能，这对于具有典型枝晶结构的模板来说是固有的困难。
Unusual complex formation of PtBr4 in THF was investigated for phenylazomethine dendrimer templates. The characteristics made it possible to reverse-order assemble platinum salts by changing the solvent composition of the dendrimers. This reverse-order assembly method enabled full-range tuning of metal ratios for hybridization, which was inherently difficult for templates with a typical dendritic structure.