Radical Chain Pathway in Formation of an Iron(IV)-Oxo Complex by Oxidation of an Iron(II) Complex with Dioxygen and Isopropanol

Radical Chain Pathway in Formation of an Iron(IV)-Oxo Complex by Oxidation of an Iron(II) Complex with Dioxygen and Isopropanol
复制标题

通过用氧气和异丙醇氧化铁(II)络合物形成铁(IV)-氧络合物的自由基链途径

DOI：
10.1039/c3cc38727e
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发表时间：
2013
期刊：
Chemical Communication
影响因子：
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通讯作者：
Yuma Morimoto; Yong-min Lee; Wonwoo Nam; Shunichi Fukuzumi
Yuma Morimoto; Yong-min Lee; Wonwoo Nam; Shunichi Fukuzumi
中科院分区：
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文献类型：
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作者：
D.Van Dam;M.Streith;J.Nizet;P.Stassart(代表);小泉京美;小泉京美;Jiyun Park ; Yuma Morimoto ; Yong-min Lee ; Wonwoo Nam ; Shunichi Fukuzumi;小泉京美;Yuma Morimoto; Yong-min Lee; Wonwoo Nam; Shunichi Fukuzumi

文献摘要

相似文献

自催化自由基链途径的证据已被报道在形成非血红素铁（IV）-氧代配合物的铁（II）配合物与分子氧和异丙醇在乙腈中在298 K的氧化。自由基链反应是由铁（IV）-氧代络合物从异丙醇中夺取氢而引发的。
Evidence of an autocatalytic radical chain pathway has been reported in formation of a non-heme iron(IV)–oxo complex by oxidation of an iron(II) complex with dioxygen and isopropanol in acetonitrile at 298 K. The radical chain reaction is initiated by hydrogen abstraction from isopropanol by the iron(IV)–oxo complex.