STRONG HOMONUCLEAR METAL-METAL BONDS
STRONG HOMONUCLEAR METAL-METAL BONDS
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DOI：
10.1021/ar50020a003
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发表时间：
1969-01-01
影响因子：
18.3
通讯作者：
COTTON, FA
中科院分区：
文献类型：
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作者：
COTTON, FA
对具有金属-金属（MM）键的化合物的有意识的研究仅仅开始于大约十年前。在此之前，已知有几种含有MM键的化合物，但它们都是偶然合成的，被认为（如果有的话）是奇闻异事，几乎没有引起（如果有的话）积极兴趣。今天，在该领域有大量的活动，很明显，MM键合是广泛的，重要的和有趣的。本报告对作者自己实验室最近的工作所作的贡献进行了简要的回顾，并没有试图给出一个全面的概述。
The deliberate study of compounds with metal-tometal (MM) bonds began only about a decade ago. Prior to that there were a few compounds known which contain MM bonds, but theyhad been made by acci-dent, were considered (if at all) as curiosities, and aroused little (if any) active interest. Today there is a great deal of activity in the field, and it has become evident that MM bonding is widespread, important, and interesting. This Account presents a brief review with emphasis on the aspects to which recent work in the author’s own laboratory has contributed; no effort is made to give a comprehensive overview.