Conversion of nitroalkanes into carboxylic acids via iodide catalysis in water.

Conversion of nitroalkanes into carboxylic acids via iodide catalysis in water.
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DOI:
10.1039/c5cc08681g
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发表时间:
2016-01
影响因子:
4.9
通讯作者:
P. Marcé;James Lynch;A. Blacker;Jonathan M. J. Williams
P. Marcé;James Lynch;A. Blacker;Jonathan M. J. Williams
中科院分区:
化学2区
文献类型:
--
作者:
P. Marcé;James Lynch;A. Blacker;Jonathan M. J. Williams

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我们报道了一种将硝基烷烃转化为羧酸的新方法,该方法在非常温和的条件下实现了这种转化。需要一定量的碘化物与简单的锌催化剂结合才能很好地转化为相应的羧酸。
We report a new method for the conversion of nitroalkanes into carboxylic acids that achieves this transformation under very mild conditions. Catalytic amounts of iodide in combination with a simple zinc catalyst are needed to give good conversions into the corresponding carboxylic acids.