How Water Dissolves in Protic Ionic Liquids
How Water Dissolves in Protic Ionic Liquids
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DOI：
10.1002/anie.201201973
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发表时间：
2012-01-01
影响因子：
16.6
通讯作者：
Atkin, Rob
中科院分区：
文献类型：
--
作者：
Hayes, Robert;Imberti, Silvia;Atkin, Rob
离子液体中的水：当等质量的水和质子离子液体硝酸乙基铵混合时，产生双连续纳米结构。这种纳米结构类似于水性表面活性剂中间相，但具有至少小一个数量级的长度尺度。水和离子液体的局部结构与纯液体中的结构惊人地相似（见图）。
Water in ionic liquids: When equal masses of water and the protic ionic liquid ethylammonium nitrate are mixed a bicontinuous nanostructure results. This nanostructure resembles aqueous surfactant mesophases but has length scales at least an order of magnitude smaller. The local structure of both the water and the ionic liquid are strikingly similar to that found in the pure liquids (see picture).