New insight into the electronic structure of SiF4: synergistic back-donation and the eighteen-electron rule

New insight into the electronic structure of SiF4: synergistic back-donation and the eighteen-electron rule
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对 SiF4 电子结构的新见解:协同反馈和十八电子规则

DOI:
10.1039/d2cp01607a
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发表时间:
2022
期刊:
Phys. Chem. Chem. Phys.
影响因子:
--
通讯作者:
Longjiu Cheng
Longjiu Cheng
中科院分区:
其他
文献类型:
--
作者:
Haoran Wang;Panpan Wu;Zhenyu Wu;Lili Shi;Longjiu Cheng

文献摘要

相似文献

Si-F σ键、协同反馈(SBD)键和18电子规则导致SiF 4在干燥空气或真空中具有较高的热稳定性。
Si–F σ bonds, synergistic back-donation (SBD) bonds and the eighteen-electron rule lead to the high thermal stability of SiF 4 in dry air or vacuum.