Dynamic Redox Systems as Electrochromic Materials: Bistability and Advanced Response
Dynamic Redox Systems as Electrochromic Materials: Bistability and Advanced Response
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DOI：
10.1002/chin.200723263
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发表时间：
2007-04
期刊：
影响因子：
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通讯作者：
Takanori Suzuki;Eisuke Ohta;Hidetoshi Kawai;K. Fujiwara;T. Fukushima
中科院分区：
文献类型：
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作者：
Takanori Suzuki;Eisuke Ohta;Hidetoshi Kawai;K. Fujiwara;T. Fukushima
“动态氧化还原系统”是给予一类化合物的名称，其可以可逆地转化为相应的带电物质，伴随着电子转移时的C-C键形成/裂解。这个帐户详细介绍了两个主要图案（六苯乙烷衍生物和丁烷-1，4-二基二阳离子），已在主要作者的小组开发。1引言2动态氧化还原性质2.1以90°扭转的二价键2.2单键的分子内氧化还原转换3基于六苯基乙烷衍生物的动态氧化还原性质的电致变色3.1四芳基二氢菲：3.2基于HPE骨架的电手性响应系统3.3基于HPE骨架的荧光氧化还原开关骨架3.4基于HPE骨架的进一步改进的分子响应系统3.5具有另一种亚芳基间隔基的HPE型氧化还原系统4基于丁烷-1，4-二基二阳离子的动态氧化还原性质的电致变色4.1 1，1，2，3，4，4-六芳基丁烷-1，4-二基二离子：原型exo系统4.2基于丁烷-1，4-二基二化的电手性响应系统4.3可逆低聚（丁烷-1，4-二基-二阳离子）物种5未来展望
‘Dynamic redox systems’ is the name given to a certain class of compounds that can be reversibly converted into the corresponding charged species accompanied by C-C bond formation/cleavage upon electron transfer. This account details the two major motifs (hexaphenylethane derivatives and butane-1,4-diyl dications) that have been developed in the principal author’s group. 1 Introduction 2 Dynamic Redox Properties 2.1 Dications Twisted by 90° 2.2 Intramolecular Redox Switching of Single Bonds 3 Electrochromism Based on the Dynamic Redox Properties of Hexaphenylethane Derivatives 3.1 Tetraaryldihydrophenanthrenes: Prototype endo Systems 3.2 Electrochiroptical Response System Based on the HPE Skeleton 3.3 Redox Switching for Fluorescence Based on the HPE -Skeleton 3.4 Further Advanced Molecular Response System Based on the HPE Skeleton 3.5 HPE-Type Redox System with Another Arylene Spacer 4 Electrochromism Based on the Dynamic Redox Properties of Butane-1,4-diyl Dications 4.1 1,1,2,3,4,4-Hexaarylbutane-1,4-diyl Dications: The Prototype exo System 4.2 Electrochiroptical Response Systems Based on the Butane-1,4-diyl Dication 4.3 Reversible Oligomerization to Oligo(butane-1,4-diyl -Dicationic) Species 5 Future Outlook