Electrochemical C(sp2)-H/N-H "formal" cross-dehydrogenative coupling of olefins with benzotriazoles for synthesis of N-vinyl benzotriazoles.
Electrochemical C(sp2)-H/N-H "formal" cross-dehydrogenative coupling of olefins with benzotriazoles for synthesis of N-vinyl benzotriazoles.
复制标题
DOI：
10.1039/d3ob01300f
复制
发表时间：
2023-10
影响因子：
3.2
通讯作者：
Jin-Feng Lv;Yueyang Tan;Ya-Nan Zhao;Dan Yang;Yan‐Hong He;Zhi Guan
中科院分区：
文献类型：
--
作者：
Jin-Feng Lv;Yueyang Tan;Ya-Nan Zhao;Dan Yang;Yan‐Hong He;Zhi Guan
The paper details an electrochemical method that couples olefins with benzotriazoles to form C(sp2)-N bonds, enabling the synthesis of N-vinyl benzotriazoles in moderate to good yields. nBu4NI functions as both an electrolyte and an iodine mediator, and the method does not require oxidants or metals. It is a highly atom-economical and clean reaction, with hydrogen as the sole byproduct.
