Copper-Catalyzed Decarboxylative Alkylselenation of Propiolic Acids with Se Powder and Epoxides
Copper-Catalyzed Decarboxylative Alkylselenation of Propiolic Acids with Se Powder and Epoxides
复制标题
铜催化硒粉和环氧化物对丙炔酸进行脱羧烷基硒化
DOI：
10.1002/adsc.202001510
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发表时间：
2021-02-09
影响因子：
5.4
通讯作者：
Wu, Ge
中科院分区：
文献类型：
--
作者：
Yao, Yujing;Wang, Caihong;Wu, Ge
研究了铜催化的丙炔酸与硒粉和环氧化合物的脱羧烷基硒化反应。该方法不仅提供了一种合成炔基硒醚的途径，而且拓展了炔基羧酸的应用范围。
A copper-catalyzed decarboxylative alkylselenation of propiolic acids with Se powder and epoxides leading to alkynyl selenides is developed. This protocol not only provides an approach to obtain alkynyl selenides with the formation of double C-Se bonds, but also expands the applicability of alkynyl carboxylic acid.